Daikin America Phase I
- Commissioning expected date
The technique uses a UV-photochemical process that breaks carbon-fluorine bonds, resulting in mineralization of targeted per- and polyfluoroalkyl substances (PFAS) in wastewater.
The technology (designed and commercialized as ClarosTechUV™) integrates with a wide range of industrial flow conditions—from lower-volume process streams to high-flow applications up to thousands of liters per minute—and is built to scale as treatment needs evolve.
Environmental purpose
The ClarosTechUV™ system has been developed to address the urgent global challenge posed by per- and polyfluoroalkyl substances (PFAS), including TFA. PFAS are resistant to natural degradation processes, resulting in their accumulation in water sources and vital ecosystems. The primary environmental purpose of the system is to permanently destroy PFAS molecules in contaminated wastewater before it ever leaves the factory, thereby reducing their presence in the environment and mitigating any associated risks.
Driving Force for Implementation
The implementation of the ClarosTechUV™ system is driven by the unique chemical properties of PFAS compounds. These substances are characterized by extremely strong carbon-fluorine bonds, making them highly resistant to conventional treatment methods and natural breakdown. There are no known biochemical pathways capable of metabolizing many PFAS molecules, which contributes to their persistence and bioaccumulation. Studies have claimed credible links between PFAS exposure and adverse health effects, particularly when these chemicals accumulate in human tissue. The public’s growing awareness of this, combined with increasing regulatory and societal pressure to address PFAS contamination, underscores the critical need for innovative technologies that can achieve cost-effective and permanent destruction of PFAS at a molecular level at the source.
Operation
Industrial wastewater is introduced directly into the reactor, where it undergoes a proprietary photochemical treatment process. During this process, ultraviolet (UV) light is used to cleave the recalcitrant carbon-fluorine bonds within PFAS molecules, leading to their mineralization. The process further relies on a propriety mixture of light-sensitive reagents comprising materials that are commonly used in water treatment applications. The result is the conversion of PFAS into inorganic fluoride, mineral carbon compounds, and short-chain hydrocarbons, which present significantly lower risks. The treated water exiting the reactor is thus substantially depleted of its PFAS content, demonstrating the system’s effectiveness in achieving destruction rather than separation or capture. The system requires minimal to zero pretreatment or pre-concentration of influent wastewater, making it highly adaptable to varying operational conditions. It can be deployed as a standalone solution or integrated into existing wastewater treatment trains, either before or after PFAS capture technologies like granular activated carbon or ion-exchange beds, and in conjunction with separation and pre-concentration systems such as reverse osmosis or nanofiltration. The system operates entirely on electric power at ambient temperature and atmospheric pressure, eliminating the need for energy-intensive pressurization, evaporation, or aerosolization steps. This results in negligible Scope I greenhouse gas emissions and aligns with industrial decarbonization strategies, particularly those using low-carbon electricity sources.
Environmental Performance
The technology has been demonstrated in commercial/industrial real world settings in the EU and the USA , targeting short and ultrashort chain species of interest in the EU like trifluoracetic acid (TFA) and perfluoropropionic acid (PFPrA):
• Pilot and commercial optimization work has confirmed the ability to reduce PFAS levels by 99.99% in industrial wastewater and treatment volumes exceeding 700 cubic meters and flow rates ranging from a few liters to thousands of liters per minute.
• Demonstrated efficient defluorination and quantitative fluorine recovery, confirming that fluorine remains contained and not released to the environment.
• Strong mineralization performance, converting total organic fluorine (TOF) in the influent to >98% inorganic free fluoride after treatment. This indicates that ClarosTechUV™ not only breaks down PFAS compounds but also efficiently converts organic fluorine into its inorganic free fluoride state, thereby enabling opportunities for circular fluorine recycling.
• Effective PFAS destruction across a wide range of influent concentrations, from sub-ppb to > 10% initial PFAS content, achieving up to 99.999% destruction of target PFAS compounds in internal lab studies and 99.99% in pilot and commercial optimization scenarios.
Basic information about the technique
The UV destruction system is flexible to accommodate varying influent composition, flow rates, and operating conditions to customer targets for PFAS destruction. The project discussed above was undertaken using systems configured for throughput over the range from approx. 10–300 cubic meters per day per reactor unit and achieved over 99.99% destruction of all target PFAS compounds under optimized conditions. Additional reactor units can be installed to further scale the process.
Associated main production process(es) and product(s): The production process is wastewater remediation, with clean water as the product
Production data: 300 cubic meters water per day
Project partners
Technology provider
As compared to:
The EU has not yet established BAT documentation that is specific to PFAS remediation or destruction.
The most relevant and widely practiced technique for waterborne PFAS destruction/mineralization is a serial strategy combining PFAS capture in granular activated carbon (GAC) beds followed by high-temperature incineration of the PFAS-laden GAC. This is the basis of comparison used in the relevant responses that follow.
Legend
Estimate is of direct (Scope I) emissions associated with the UV destruction process relative to the reference case of incineration with or without pre-concentration in granular activated carbon beds, which results in Scope I emissions associated with onsite fuel use and direct combustion of PFAS and associated sorbents.
The ClarosTechUV™ process runs entirely on electric power and generates negligible Scope I emissions of CO2 or other GHGs. Note that quantitative carbon intensities have not been entered because GHG emissions that result from the reference case (PFAS incineration) have not been fully quantified.
Energy consumption varies based on influent water characteristics and PFAS destruction targets. Benchmark values that have been obtained with customers on a scale of tens of cubic meters per day are in the range from 2-10 kWh of electric energy input per cubic meter treated per log (90%) destruction of PFAS targets.
Other pollutant is PFAS products of incomplete combustion (PIC), which result from GAC incineration (reference case) under un-optimized conditions. The present technology of UV-destruction produces no gas, vapor, or aerosol emissions containing PIC.
Pollutant is PFAS remnants, particularly short and ultra-short chain PFAS with trifluoroacetic acid (TFA) as a representative example.
The reference case of GAC adsorption plus incineration release short and ultra-short chain PFAS molecules since they adsorb weakly and tend to wash through activated carbon beds. Pilot and pre-commercial work has included studies in which ClarosTechUV™ was deployed downstream of GAC adsorption operations, where it destroyed over 99.99% of PFAS remnants in the wastewater under optimized conditions.
The effluent flow from the UV Photochemical process comprises inorganic fluoride and mineralized carbon-containing fragments, whose concentration increases to an extent that is commensurate with the total extent of PFAS destruction and defluorination. Mass-balance measurements performed in pilot and commercial work show that overall fluorine levels remain conserved within the aqueous medium, with total defluorination exceeding 98.5% under optimized conditions. Claros works with customers to identify optimal destruction conditions, characterize residual products (if any), and balance treatment times with additional strategies, such as effluent polishing, for residual management.
Industrial symbiosis resource flow:
Baseline situation: Landfilled
Circular fluoride recovery is proposed and validated in laboratory trials, but not yet demonstrated with customers at scale.
Two-phase pilot study (phase I) and commercial optimization run (phase II) project comprising continuous PFAS destruction in wastewater stream at industrial facility involved in polymer manufacturing in the southeast united states.
Project costs vary dramatically with system configuration and scale. Prospective partners and other stakeholders are encouraged to contact Claros Technologies to discuss process economics for a particular application.